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<!doctype html>
<html lang="en">
<head>
<meta charset="utf-8">
<meta name="viewport" content="width=device-width, initial-scale=1.0, maximum-scale=1.0, user-scalable=no">
<title>A.Kononov Disputation</title>
<link rel="shortcut icon" href="#">
<link rel="stylesheet" href="dist/reset.css">
<link rel="stylesheet" href="dist/reveal.css">
<link rel="stylesheet" href="/css/reveal.scss">
<link rel="stylesheet" href="css/lauout.scss">
<link rel="stylesheet" href="dist/theme/black.css">
<link rel="stylesheet" href="css/mystyl.css">
<!-- Theme used for syntax highlighted code -->
<link rel="stylesheet" href="plugin/highlight/monokai.css">
<style>
@keyframes draw {
to {
stroke-dashoffset: 0;
}
}
</style>
</head>
</head>
<body>
<div class="reveal">
<div class="menubar">
<ul class="menu"></ul> <!-- Keep this empty -->
</div>
<div class="slides">
<section id ="title-slide" data-visibility="uncounted">
<h2 class="fragment current-visible" style="font-size:90%;margin-top:100px;">Fullerene and bismuth clusters on nanostructured
oxide films </br><font size="6" style="text-transform: none;" >Influence of nearest neighbors and
surface contribution on charging energy</font></h2>
<!-- <h2>Fullerene und Bismutcluster </br>auf </br>Al<sub>2</sub>O<sub>3</sub>||Ni<sub>3</sub>Al(111)</h2> -->
<!-- <div class="r-stack">
<h2 class="fragment current-visible" style="font-size:90%;margin-top:100px;">Fullerene and bismuth clusters on nanostructured
oxide films: </br><font size="6">Influence of nearest neighbors and
surface contribution on charging energy</font></h2>
<h2 class="fragment current-visible" style="font-size:90%;margin-top:100px;text-transform: none;">Fullerene and bismuth clusters on nanostructured oxide films: </br><font size="6">Influence of nearest neighbors and surface contribution on charging energy</font></h2>
<h2 class="fragment current-visible" style="font-size:90%;margin-top:100px;">
Fulleren- und Bismut-Cluster auf nanostrukturierten Oxidschichten:
</br><font size="6">Einfluss der nächsten Nachbarn und des Oberflächenbeitrags auf die Ladungsenergie</font>
</h2>
<h2 class="fragment" style="font-size:90%;margin-top:100px;text-transform: none;">
Fulleren- und Bismut-Cluster auf nanostrukturierten Oxidschichten:
</br><font size="6">Einfluss der nächsten Nachbarn und des Oberflächenbeitrags auf die Ladungsenergie</font>
</h2>
</div> -->
<img src="/pictures/Opening/title_page_oppening.svg" width="90%">
</section>
<section data-name ="Motivation">
<section>
<h2>Was ist ein Cluster?</h2>
<p class = "fragment danger" style ="font-size:80%;">Cluster sind verbindungen von mindestens 3 Atomen.</p>
<div class = 'col-container'>
<div class = 'col-one' style="margin: 0px 0px 0px 10px">
<div id ="atom_my_ass2">
<h3 class = "fragment" style="right:100px;margin: -30px 0px 0px 0px;"><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#atom_my_ass2');" ><i>🔎︎</i></button>Atom</h3>
<span class="fragment" data-zoom-trigger='{"selector": "#atom_my_ass2", "scale": 1}'></span>
<div class = 'col-container'>
<div class = 'col-one'>
<h5 class = "fragment">klassisch</h5>
<img class = "fragment" src="pictures/AtomicOrbitals/Atom-as-solar-system.svg" width="100%">
</br>
<div class="r-stack" width ="100%;">
<img class = "fragment current-visible" src="pictures/AtomicOrbitals/Atom-as-solar-system-animate.svg" width="100%">
<h6 class = "fragment">Wenn Atomkern ein Apfel wäre</h6>
<img class = "fragment current-visible" src="pictures/AtomicOrbitals/red-apple-svgrepo-com.svg" width="70%">
<img class = "fragment current-visible" src="pictures/AtomicOrbitals/Dortmund-Innenstadt2.png" width="100%">
<img class = "fragment current-visible" src="pictures/AtomicOrbitals/Dortmund-Innenstadt3.png" width="100%">
<img class = "fragment" src="pictures/AtomicOrbitals/Dortmund-Innenstadt4.png" width="100%">
<!-- <img class = " shrink" src="pictures/AtomicOrbitals/Dortmund-Innenstadt2.png" width="30%"> -->
<!-- <img class = " current-visible" src="pictures/AtomicOrbitals/Dortmund-Innenstadt2.png" width="30%"> -->
</div>
</div>
<div class = 'col-tree' style="margin: 0px 0px 0px 10px ;">
<h5 class = "fragment">quantenmechanisch</h5>
<div class = 'col-container'>
<div class = 'col-two'>
<div class ="fragment" style="font-size:65%;">
\(\psi_{n\ell m}(r,\theta,\phi) =
\sqrt{
\left(\frac{2}{na_0}\right)^3\, \frac{(n-\ell-1)!}{2n[(n+\ell)!]}
}
e^{-r / na_0}
\left(\frac{2r}{na_0}\right)^\ell
L_{n-\ell-1}^{2\ell+1} \cdot Y_\ell^m(\theta, \phi)
\)
</div>
<div class ="fragment" >
<img class = "image" width = "80%" style="float:left;" src="pictures/Solids/Filling_levels.svg">
<div class="left-bottom-under-image"><font size="2.5">K.Efthimios, and J. D. Joannopoulos. "Quantum Theory of Materials" 2019.</font></div>
</div>
</div>
<div class = 'col-one'>
<!-- <div class="simple-gallery--thumbs">
<ul>
<li>
<div class =" image-container" style ="right: 230px;top: 30px;">
<img class = "image_in_col" width = "100%"" src="pictures/AtomicOrbitals/quantenmechanisch/orbitals/animations/(1, 0, 0)orbital5000-SF8LU8.gif">
<div class="top-right">1 0 0</div>
</div>
</li>
<li>
<div class =" image-container" style ="right:50px;bottom: 160px;" >
<img class = "image_in_col" width = "100%" src="pictures/AtomicOrbitals/quantenmechanisch/orbitals/animations/(2, 1, 0)orbital5000-SF8LXD.gif">
<div class=" top-right">2 1 0</div>
</div>
</li>
<li>
<div class =" image-container" style ="right:50px; bottom: 150px;">
<img class = "image_in_col" width = "100%" src="pictures/AtomicOrbitals/quantenmechanisch/orbitals/animations/(3, 1, -1)orbital5000-SF8LZ5.gif">
<div class="bottom-right">3 1 -1</div>
</div>
</li>
</ul>
</div> -->
<div class="fragment simple-gallery simple-gallery--thumbs">
<ul>
<li>
<div class ="fragment image-container" >
<img class = "image_in_col" width = "85%" src="pictures/AtomicOrbitals/quantenmechanisch/orbitals/animations/(1, 0, 0)orbital5000-SF8LU8.gif">
<div class="top-right">1 0 0</div>
</div>
</li>
<li>
<div class ="fragment image-container" >
<img class = "image_in_col" width = "85%" src="pictures/AtomicOrbitals/quantenmechanisch/orbitals/animations/(2, 1, 0)orbital5000-SF8LXD.gif">
<div class="top-right">2 1 0</div>
</div>
</li>
<li>
<div class ="fragment image-container" >
<img class = "image_in_col" width = "85%" src="pictures/AtomicOrbitals/quantenmechanisch/orbitals/animations/(3, 1, -1)orbital5000-SF8LZ5.gif">
<div class="top-right">3 1 -1</div>
</div>
</li>
</ul>
</div>
</div>
</div>
</div>
</div>
</div>
<span class="fragment" data-zoom-trigger='{"selector": "#atom_my_ass", "scale": 1}'></span>
<div id="molecule_my_ass" class = 'col-container' style="margin: 5px 0px 0px 0px">
<div class = 'col'>
<h3 class="fragment" style="margin: -30px 0px 0px 0px"><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#molecule_my_ass');" ><i>🔎︎</i></button>Molekül</h3>
<span class="fragment" data-zoom-trigger='{"selector": "#molecule_my_ass", "scale": 1}'></span>
<!-- <img class = "image" width = "50%" src="pictures/MolecularOrbitals/h2o_orbitals.gif"> -->
<!-- <div class ="fragment image-container">
<img class = "image" width = "90%" src="pictures/MolecularOrbitals/H2O.svg">
<div class="citaion-bottom-right">https://water.lsbu.ac.uk/water/h2o_orbitals.html</div>
<div class="citaion2-bottom-right">physikmdb.uni-graz.at</div>
</div> -->
<div class="r-stack">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-1.svg" width = "100%">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-2.svg" width = "100%">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-3.svg" width = "100%">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-4.svg" width = "100%">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-5.svg" width = "100%">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-6.svg" width = "100%">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-7.svg" width = "100%">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-8.svg" width = "100%">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-8.1.svg" width = "100%">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-9.svg" width = "100%">
<img class="fragment current-visible " src="pictures/MolecularOrbitals/H2O-10.svg" width = "100%">
<img class="fragment" src="pictures/MolecularOrbitals/H2O-11.svg" width = "100%">
</div>
</div>
<div class = 'col-tree'>
<h3 class = "fragment" style="margin: -30px 0px 0px 0px">Festkörper (Bulk)</h3>
<div class="col-container">
<div class ="col">
<div class="r-stack">
<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid1.svg" width="100%" >
<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid2.svg" width="100%" >
<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid3.svg" width="100%" >
<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid4.svg" width="100%" >
<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid5.svg" width="100%" >
<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid6.svg" width="100%" >
<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid7.svg" width="100%" >
<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid8.svg" width="100%" >
<img class = "fragment" src="pictures/Solids/from--atom-to-solid9.svg" width="100%" >
</div>
</div>
<div class ="col">
<img class = "fragment" src="pictures/Solids/Silicone_band_structure/Si-bandStrukture-whole.svg" width="100%" >
</div>
</div>
</div>
</div>
</div>
<span class="fragment" data-zoom-trigger='{"selector": "#molecule_my_ass", "scale": 1}'></span>
<div class = 'col-one' style="margin: 0px 10px 0px 0px">
<div id ="cluster_my_ass">
<h3 class = "fragment" style="margin: -30px 0px 0px 0px;" > <button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#cluster_my_ass');" ><i>🔎︎</i></button> Cluster</h3>
<h4 class = "fragment" >Warum so besonders?</h4>
<span class="fragment" data-zoom-trigger='{"selector": "#cluster_my_ass", "scale": 1}'></span>
<div class="col-container">
<div class ="col-two">
<h5 class = "fragment">Cluster VS Bulk:</h5>
<div class="col-container">
<div class ="col-one">
<!-- <ul class = "fragment normal-text">
<li>Eigenschaften ändern sich durch Hinzufügen/Entfernen eines Atoms</li>
<li>Keine regelmäßige Atomanordnung (Polyeder)</li>
<li>Vielfältige Strukturvariationen</li>
</ul> -->
<div class="fragment normal-text danger"> Änderung der Eigenschaften mit n</div>
<div class="fragment r-stack" width ="100%;">
<div class = "fragment current-visible custom-cursor">
<object type="image/svg+xml" data="pictures/Cluster-vs-solids_molecules/Hg_sizedepend_still_frame.svg" width="100%"></object>
<div class="left-bottom-under-image"><font size="2.5">K. Rademann et al., Phys. Rev. Lett. 59, 2319–2321 (1987)</font></div>
</div>
<div class ="fragment custom-cursor" id="fragment_Hg-clusters">
<object id="svgHg-clusters" typecc="image/svg+xml" data="pictures/Cluster-vs-solids_molecules/Hg_sizedepend.svg" width="100%" ></object>
<div class="left-bottom-under-image"><font size="2.5">K. Rademann et al., Phys. Rev. Lett. 59, 2319–2321 (1987)</font></div>
</div>
</div>
<div class="fragment normal-text danger ">Ein Atom macht Unterschied</div>
<div class="fragment normal-text danger">Potenziell tunable</div>
</div>
<div class ="col-one">
<div class="fragment normal-text danger" > Keine periodische Einheitszelle</div>
<object class="fragment" id="html_myAss" type="text/html" data="pictures/Cluster-vs-solids_molecules/Bi_2_13.html" width="18%" height ="30%"></object>
<object id="html_myAss2" class="fragment" type="text/html" data="pictures/Cluster-vs-solids_molecules/Bi_3_55.html" width="30%" height ="30%"></object>
<object id="html_myAss3" class="fragment" type="text/html" data="pictures/Cluster-vs-solids_molecules/Bi_4_147.html" width="40%" height ="30%"></object>
<br>
<object id="html_myAss4" class="fragment" type="text/html" data="pictures/Cluster-vs-solids_molecules/Bi_5_309.html" width="45%" height ="40%"></object>
<object id="html_myAss5" class="fragment" type="text/html" data="pictures/Cluster-vs-solids_molecules/Bi_6_561.html" width="50%" height ="40%" ></object>
</div>
</div>
</div>
<div class ="col-one">
<h5 class = "fragment">Cluster VS Molekülen:</h5>
<div class="fragment normal-text danger "> Vielfältige Strukturvariationen </div>
<div class ="fragment" id="fragment_Ar-clusters">
<object id="svgAr-clusters" type="image/svg+xml" data="pictures/Cluster-vs-solids_molecules/Ar_seven_geo_transitions_animated2.svg" width="85%" ></object>
<div class="left-bottom-under-image"><font size="2.5">D. J. Wales et al., J. Chem. Phys. 92, 4283–4295 (1990).</font></div>
</div>
</div>
</div>
</div>
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<div id="wie_gemacht_my_ass">
<h4 class = "fragment" ><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#wie_gemacht_my_ass');" ><i>🔎︎</i></button>Wie werden sie gemacht?</h4>
<span class="fragment" data-zoom-trigger='{"selector": "#wie_gemacht_my_ass", "scale": 1}'></span>
<div class="col-container">
<div class="col-one">
<h6 class = "fragment" >Chemisch: "Self-assembly" in Lösung</h6>
<div class = "fragment">
<img src="pictures/Nanoparticals_howtomade/NP-in-solutions_only_one.svg" width="100%" >
<br>
<div class="left-bottom-under-image"><font size="2.5">K. Xia et al., Nat Commun. 15, 851 (2024).</font></div>
</div>
</div>
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<h6 class = "fragment" >Aggregation in der Gasphase</h6>
<div class = "fragment">
<img src="pictures/Nanoparticals_howtomade/Gas aggregation technique2.svg" width="100%" >
<div class="left-bottom-under-image" style="line-height:.8"><font size="2.5">Koch, Siete Adriaan. / Functionality and dynamics of deposited metal nanoclusters. s.n., 2005. 167 p.</font></div>
</div>
</div>
<div class="col-one">
<h6 class = "fragment" >"Self-assembly" auf Oberflächen</h6>
<!-- <img id= "pvd_growth" src="pictures/Nanoparticals_howtomade/pvd-growth.svg" width="100%" > -->
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</div>
</div>
<div class ="fragment danger" style ="text-align:left;"><font size="6">"Clusters: A bridge across the disciplines of physics and chemistry"</font><div class="left-bottom-under-image"><font size="4">P. Jena et al., Proc. Natl. Acad. Sci. U.S.A. 103, 10560–10569 (2006).</font></div></div>
</div>
</div>
</div>
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</section>
<section>
<h2>Motivation</h2>
<div class="col-container">
<div class="col-one">
<h4 class = "fragment">Photoemission an Blei Cluster</h4>
<div class="fragment">
<img src="pictures/Motivation/core_hoel_screening_sep1.svg" width="85%"/>c
<div class="left-bottom-under-image" style="margin-left:10px;"><font size="4">V. Senz et al., Physical Review Letters. 102, 3–6 (2009)</font></div>
</div>
</div>
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<h4 class = "fragment">Photoemission Grund-Prinzip</h4>
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<h4 class = "fragment">Blei Cluster nach Größe</h4>
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<div class = "fragment current-visible" >
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<div class="left-bottom-under-image"><font size="4">V. Senz et al., Physical Review Letters. 102, 3–6 (2009)</font></div>
</div>
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<div class="left-bottom-under-image"><font size="4">V. Senz et al., Physical Review Letters. 102, 3–6 (2009)</font></div>
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</div>
</div>
</section>
</section>
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<h2>Was ist ein Cluster?</h2>
<p class = " danger" style ="font-size:80%;">Cluster sind verbindungen von mindestens 3 Atomen.</p>
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<h3 class = "" style="right:100px;margin: -30px 0px 0px 0px;"><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#atom_my_ass');" ><i>🔎︎</i></button>Atom</h3>
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<h5 class = "">klassisch</h5>
<img class = "" src="pictures/AtomicOrbitals/Atom-as-solar-system.svg" width="100%">
</br>
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<img class = " current-visible" src="pictures/AtomicOrbitals/Atom-as-solar-system-animate.svg" width="100%">
<h6 class = "">Wenn Atomkern ein Apfel wäre</h6>
<img class = " current-visible" src="pictures/AtomicOrbitals/red-apple-svgrepo-com.svg" width="70%">
<img class = " current-visible" src="pictures/AtomicOrbitals/Dortmund-Innenstadt2.png" width="100%">
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<h5 class = "">quantenmechanisch</h5>
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<div class ="" style="font-size:65%;">
\(\psi_{n\ell m}(r,\theta,\phi) =
\sqrt{
\left(\frac{2}{na_0}\right)^3\, \frac{(n-\ell-1)!}{2n[(n+\ell)!]}
}
e^{-r / na_0}
\left(\frac{2r}{na_0}\right)^\ell
L_{n-\ell-1}^{2\ell+1} \cdot Y_\ell^m(\theta, \phi)
\)
</div>
<div class ="" >
<img class = "image" width = "80%" style="float:left;" src="pictures/Solids/Filling_levels.svg">
<div class="left-bottom-under-image"><font size="2.5">K.Efthimios, and J. D. Joannopoulos. "Quantum Theory of Materials" 2019.</font></div>
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<span class="fragment" data-zoom-trigger='{"selector": "#atom_my_ass", "scale": 1}'></span>
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<h3 class = "fragment" style="margin: -30px 0px 0px 0px"><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#molecule_my_ass');" ><i>🔎︎</i></button>Molekül</h3>
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<img class = "image" width = "90%" src="pictures/MolecularOrbitals/H2O.svg">
<div class="citaion-bottom-right">https://water.lsbu.ac.uk/water/h2o_orbitals.html</div>
<div class="citaion2-bottom-right">physikmdb.uni-graz.at</div>
</div> -->
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<h3 class = "fragment" style="margin: -30px 0px 0px 0px">Festkörper (Bulk)</h3>
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<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid6.svg" width="100%" >
<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid7.svg" width="100%" >
<img class = "fragment current-visible" src="pictures/Solids/from--atom-to-solid8.svg" width="100%" >
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<span class="fragment" data-zoom-trigger='{"selector": "#molecule_my_ass", "scale": 1}'></span>
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<div id ="cluster_my_ass">
<h3 class = "fragment" style="margin: -30px 0px 0px 0px;" > <button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#cluster_my_ass');" ><i>🔎︎</i></button> Cluster</h3>
<h4 class = "fragment" >Warum so besonders?</h4>
<span class="fragment" data-zoom-trigger='{"selector": "#cluster_my_ass", "scale": 1}'></span>
<div class="col-container">
<div class ="col-two">
<h5 class = "fragment">Cluster VS Bulk:</h5>
<div class="col-container">
<div class ="col-one">
<!-- <ul class = "fragment normal-text">
<li>Eigenschaften ändern sich durch Hinzufügen/Entfernen eines Atoms</li>
<li>Keine regelmäßige Atomanordnung (Polyeder)</li>
<li>Vielfältige Strukturvariationen</li>
</ul> -->
<div class="fragment normal-text danger"> Änderung der Eigenschaften mit n</div>
<div class="fragment r-stack" width ="100%;">
<div class = "fragment current-visible custom-cursor">
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<div class="left-bottom-under-image"><font size="2.5">K. Rademann et al., Phys. Rev. Lett. 59, 2319–2321 (1987)</font></div>
</div>
<div class ="fragment custom-cursor" id="fragment_Hg-clusters">
<object id="svgHg-clusters" typecc="image/svg+xml" data="pictures/Cluster-vs-solids_molecules/Hg_sizedepend.svg" width="100%" ></object>
<div class="left-bottom-under-image"><font size="2.5">K. Rademann et al., Phys. Rev. Lett. 59, 2319–2321 (1987)</font></div>
</div>
</div>
<div class="fragment normal-text danger ">Ein Atom macht Unterschied</div>
<div class="fragment normal-text danger">Potenziell tunable</div>
</div>
<div class ="col-one">
<div class="fragment normal-text danger" > Keine periodische Einheitszelle</div>
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<h5 class = "fragment">Cluster VS Molekülen:</h5>
<div class="fragment normal-text danger "> Vielfältige Strukturvariationen </div>
<div class ="fragment" id="fragment_Ar-clusters">
<object id="svgAr-clusters" type="image/svg+xml" data="pictures/Cluster-vs-solids_molecules/Ar_seven_geo_transitions_animated2.svg" width="85%" ></object>
<div class="left-bottom-under-image"><font size="2.5">D. J. Wales et al., J. Chem. Phys. 92, 4283–4295 (1990).</font></div>
</div>
</div>
</div>
</div>
<span class="fragment" data-zoom-trigger='{"selector": "#cluster_my_ass", "scale": 1}'></span>
<div id="wie_gemacht_my_ass">
<h4 class = "fragment" ><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#wie_gemacht_my_ass');" ><i>🔎︎</i></button>Wie werden sie gemacht?</h4>
<span class="fragment" data-zoom-trigger='{"selector": "#wie_gemacht_my_ass", "scale": 1}'></span>
<div class="col-container">
<div class="col-one">
<h6 class = "fragment" >Chemisch: "Self-assembly" in Lösung</h6>
<div class = "fragment">
<img src="pictures/Nanoparticals_howtomade/NP-in-solutions_only_one.svg" width="100%" >
<br>
<div class="left-bottom-under-image"><font size="2.5">K. Xia et al., Nat Commun. 15, 851 (2024).</font></div>
</div>
</div>
<div class="col-two">
<h6 class = "fragment" >Aggregation in der Gasphase</h6>
<div class = "fragment">
<img src="pictures/Nanoparticals_howtomade/Gas aggregation technique2.svg" width="100%" >
<div class="left-bottom-under-image" style="line-height:.8"><font size="2.5">Koch, Siete Adriaan. / Functionality and dynamics of deposited metal nanoclusters. s.n., 2005. 167 p.</font></div>
</div>
</div>
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<h6 class = "fragment" >"Self-assembly" auf Oberflächen</h6>
<!-- <img id= "pvd_growth" src="pictures/Nanoparticals_howtomade/pvd-growth.svg" width="100%" > -->
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</div>
<div class ="fragment danger" style ="text-align:left;"><font size="6">"Clusters: A bridge across the disciplines of physics and chemistry"</font><div class="left-bottom-under-image"><font size="4">P. Jena et al., Proc. Natl. Acad. Sci. U.S.A. 103, 10560–10569 (2006).</font></div></div>
</div>
</div>
</div>
<span class="fragment" data-zoom-trigger='{"selector": "#wie_gemacht_my_ass", "scale": 1}'></span>
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<section data-visibility="uncounted"><!-- <section data-name ="Cluster im Altag"> -->
<h2>Cluster im Alltag</h2>
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<h4 class = "fragment">Cluster in der Antike </h4>
<h5 class = "fragment">"Lykurgos-Becher" Rom ca. 4.Jahrhundert</h5>
<br>
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<div class ="image"><img src="pictures/Cluster-in-real-life/sticker1.webp" width="55%" >
<br>
<img src="pictures/Cluster-in-real-life/sticker.webp" width="55%" ><br>
<div style="float:left;line-height:0.6;"><font size="5">"British Museum" www.britishmuseum.org</font></div>
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<h4 class = "fragment">Cluster als Katalysator</h4>
</br>
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<img src="pictures/Cluster-in-real-life/Cluster-catalyse.svg" width="95%"/>
<div class="left-bottom-under-image"><font size="5"> H. Wang et al., Nat Catal. 4, 418–424 (2021)</font></div>
</div>
</br>
<h4 class = "fragment">Cluster in der Medizin</h4>
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<h5>Gadalonium (Gd) in C<sub>60</sub>-Cluster-Käfig alt Kontrast-Mittel für MRT</h5>
<img src="pictures/Cluster-in-real-life/Cluster-in-medizin2.svg" width="80%"/>
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<div class="left-bottom-under-image"><font size="5"> F. D’Souza et al., Handbook of Carbon Nano Materials vol. 5 (2014)</font></div>
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<h4 class = "fragment"><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#cluster_tv_my_ass');" ><i>🔎︎</i></button> Cluster in TVs (Quantum Dots QDs)</h4>
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<img src="pictures/Cluster-in-real-life/Qunatum-dots-spectra.svg" width="90%"/>
<div class="left-bottom-under-image"><font size="5">Z. Wen et al., J. Phys. D: Appl. Phys. 54, 213002 (2021)</font></div>
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<!-- <div class="left-bottom-under-image"><font size="3.5">Z. Wen et al., J. Phys. D: Appl. Phys. 54, 213002 (2021)</font></div> -->
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</div>
<!--
<aside class ="notes" data-markdown>
1. LGP: Light Guide Plate: ist eine transparente Acrylplatte aus optischem PMMA, PS oder einer Kombination aus zwei Harzen (damals als MS-Materialien bekannt).
Es funktioniert, indem es Licht von den Rändern lenkt und es gleichmäßig über die obere Oberfläche des Panels verteilt.
2. QDEFs: QD Enhancement Films
3. OLED: Organic Light-Emitting Diod:
4. EL QDs: Electro Luminescent Quantum Dots:
</aside> -->
</section>
</section>
<section id ="old_Motivation" data-visibility="uncounted">
<h2>Motivation</h2>
<div class="col-container">
<div class="col-one">
<h4 class = "fragment">Photoemission an Blei Cluster</h4>
<div class="fragment">
<img src="pictures/Motivation/core_hoel_screening_sep1.svg" width="85%"/>c
<div class="left-bottom-under-image" style="margin-left:10px;"><font size="4">V. Senz et al., Physical Review Letters. 102, 3–6 (2009)</font></div>
</div>
</div>
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<h4 class = "fragment">Photoemission Grund-Prinzip</h4>
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<h4 class = "fragment">Blei Cluster nach Größe</h4>
<div class="r-stack" width ="100%;">
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<object type="image/svg+xml" data="pictures/Motivation/core_hoel_screening_sep2_still_frame.svg" width="100%"></object>
<div class="left-bottom-under-image"><font size="4">V. Senz et al., Physical Review Letters. 102, 3–6 (2009)</font></div>
</div>
<div class = "fragment" id ="fragemnt_Pb_corehole">
<object id="svgPb_corehole" type="image/svg+xml" data="pictures/Motivation/core_hoel_screening_sep2.svg" width="100%"></object>
<div class="left-bottom-under-image"><font size="4">V. Senz et al., Physical Review Letters. 102, 3–6 (2009)</font></div>
</div>
</div>
</div>
</div>
</section>
<section id="old_Experiment" data-visibility="uncounted">
<section data-visibility="uncounted" >
<h2><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#vacuum_uber_my_ass');" ><i>🔎︎</i></button>Ultra-Hoch-Vakuum Anlage</h2>
<div class="col-container">
<div class="col-two r-stack">
<div style="float:left;margin:0 0 0 50px; font-size:29.5pt;" >
<ul>
<li>Ultra reine Umgebung (Druck ~ 1x10<sup>-10</sup> mbar)</li>
<li> Hohe Preparations-Temperaturen sind möglich (bis 1000°C)</li>
<li> Messen bei Tiefen-Temperaturen bis 10K (~ -260°C)</li>
</ul>
</div>
<img style="float:left;margin:200px 0 0 100px;" class ="fragment " data-fragment-index="1 2" src="pictures/Experiment/facility.svg" width="80%"/>
<img style="float:left;margin:200px 0 0 100px;" class ="fragment " data-fragment-index="3" src="pictures/Experiment/facility-sample.svg" width="80%"/>
</div>
<div class="col-one" style="margin:0 0px 0 0;">
<div id="vacuum_uber_my_ass" class="r-stack" width ="100%;">
<!-- <object class="fragment current-visible" type="image/svg+xml" data="pictures/Experiment/vakuum-im-ueberblick-poster.svg" width="75%"/></object> -->
<div class="fragment current-visible" >
<img src="pictures/Experiment/vakuum-im-ueberblick-poster.svg" width="70%"/>
<div class="left-bottom-under-image"><font size="3.5"> Paul Scherrer Institut, Villingen, CH</font></div>
</div>
<!-- <span class="fragment" data-zoom-trigger='{"selector": "#vacuum_uber_my_ass", "scale": 1}'></span> -->
<div id ="hold_my_ass" class = "fragment">
<div id="ups_my_ass">
<h4 ><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#ups_my_ass');" ><i>🔎︎</i></button>Ultraviolet-Photo-Emission (UPS)</h4>
<object id="animate_my_ass_photoemission" type="image/svg+xml" data="pictures/Experiment/Photoemission.svg" width="90%"/></object>
</div>
<div id="element-to-zoom" >
<h4 class = "fragment" style="font-size:80%"><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#element-to-zoom');" ><i>🔎︎</i></button>Scanning-Tunneling-Microscope (STM)</h4>
<div class="r-stack">
<img class = "fragment current-visible" src="pictures/Experiment/stm.svg"" width="90%" />
<!-- <object class = "fragment" type="image/svg+xml" data="pictures/Experiment/stm.svg" width="90%"/></object> -->
<img class = "fragment current-visible" src="pictures/Experiment/stm_lateral_structure_broadening-still-frame.svg"" width="90%" />
<object id="stm-bradening" class = "fragment" type="image/svg+xml" data="pictures/Experiment/stm_lateral_structure_broadening.svg" width="90%"/></object>
</div>
</div>
</div>
<!-- <span class="fragment" data-zoom-trigger='{"selector": "#element-to-zoom", "scale": 1}'></span>
<span class="fragment" data-zoom-out-trigger></span>
-->
</div>
</div>
</div>
</section>
<section>
<h2>Untersuchte Systeme</h2> <!-- C<sub>60</sub>, Bismut und Al<sub>2</sub>O<sub>3</sub>||Ni<sub>3</sub>Al -->
<div class="col-container">
<div class="col-one" style="margin-left:15px">
<div id="c60_system_my_ass">
<h4 class="fragment style="margin: 0 0 0 0" ><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#c60_system_my_ass');" ><i>🔎︎</i></button>Fullerene C<sub>60</sub></h4>
<div class ="r-stack" >
<img class="fragment current-visible" src="pictures/Samples/fulleren.svg" width="100%"/></img>
<img class="fragment current-visible" src="pictures/Samples/fulleren-sides.svg" width="100%"/></img>
<img class="fragment" src="pictures/Samples/fulleren-sides-energy.svg" width="100%"/></img>
<!-- <object class="fragment" type="image/svg+xml" data="pictures/Samples/fulleren_flat.svg" width="50%"/></object> -->
</div>
</div>
<div id="bi_system_my_ass">
<h4 class="fragment"><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#bi_system_my_ass');" ><i>🔎︎</i></button>Bismut</h4>
<div class ="r-stack" >
<img class="fragment current-visible" src="pictures/Samples/bi_crystall.svg" width="100%"/></img>
<img class="fragment current-visible" src="pictures/Samples/bi_crystall-bandstr.svg" width="100%"/></img>
<img class="fragment" src="pictures/Samples/bi_crystall-bandstr-energy.svg" width="100%"/></img>
</div>
<div class="fragment">
<img style="margin-left:10px" src="pictures/Samples/Wismuth-sticker.webp" width="30%"/></img><br>
<div class="left-bottom-under-image"><font size="3.5"> https://en.wikipedia.org/wiki/File:Wismut_Kristall_und_1cm3_Wuerfel.jpg</font></div>
</div>
</div>
</div>
<div class="col-one">
<div id="al_substrat_my_ass">
<h4 class="fragment"> <button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#al_substrat_my_ass');" ><i>🔎︎</i></button> Substrat: Al<sub>2</sub>O<sub>3</sub>||Ni<sub>3</sub>Al(111)</h4>
<div class ="r-stack" >
<img class="fragment current-visible" src="pictures/Samples/Al2O3_quer.svg" width="100%"/></img>
<img class="fragment" src="pictures/Samples/Al2O3_quer-oberflaeche.svg" width="100%"/></img>
</div>
</div>
<div id="ablauf_my_ass">
<h4 class="fragment" > <button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#ablauf_my_ass');" ><i>🔎︎</i></button>Experiment Ablauf</h4>
<div class ="r-stack" >
<img class="fragment current-visible" src="pictures/Samples/Ablauf-Depo.svg" width="100%"/></img>
<img class="fragment current-visible" src="pictures/Samples/Ablauf-Tempern.svg" width="100%"/></img>
<img class="fragment current-visible" src="pictures/Samples/Ablauf-Messen.svg" width="100%"/></img>
<img class="fragment" src="pictures/Samples/Ablauf-Repeat.svg" width="100%"/></img>
</div>
</div>
</div>
</section>
<section>
<h2 style="margin-bottom:0pxgf">Resultate</h2>
<div class = 'col-container'>
<div class = 'col-one' style="margin: 0px 0px 0px 10px">
<h3 class="fragment" style="margin: -50px 0px 0px 0px" >Messung</h3>
<div id ="c60_messung_my_ass">
<h4 class="fragment" ><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#c60_messung_my_ass');" ><i>🔎︎</i></button> C<sub>60</sub> Fullerene</h4>
<img class="fragment" src="pictures/Results/C60-Mesung-Result2.svg" width="100%"/></img>
<!-- <object class="fragment" type="image/svg+xml" data="pictures/Results/C60-Mesung-Result.svg" width="50%"/></object> -->
</div>
<div id="bi_messung_my_ass">
<h4 class="fragment" ><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#bi_messung_my_ass');" ><i>🔎︎</i></button> Bismut</h4>
<img class="fragment" src="pictures/Results/Bismuth-Mesung-Result2.svg" width="89%"/></img>
</div>
</div>
<div class = 'col-one' style="margin: 0px 0px 0px 0px">
<h3 class="fragment" style="margin: -50px 0px 0px 0px" >Model</h3>
<div id="c60_model_my_ass">
<h4 class="fragment" ><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#c60_model_my_ass');" ><i>🔎︎</i></button>C<sub>60</sub> Fullerene</h4>
<!-- <img class="fragment" src="pictures/Results/c60-model.svg" width="100%"/></img>-->
<div class ="r-stack" >
<img class="fragment current-visible" src="pictures/Results/c60-model-C60-free.svg" width="90%"/></img>
<img class="fragment current-visible" src="pictures/Results/c60-model-C60-surface.svg" width="90%"/></img>
<img class="fragment current-visible" src="pictures/Results/c60-model-C60-neighbours.svg" width="90%"/></img>
<img class="fragment" src="pictures/Results/c60-model-C60-Udiff.svg" width="90%"/></img>
</div>
</div>
<h4 class="fragment" ><button class ="my_zoom_button" type="button" value="" onclick="zoomElement('#zoom_me_hard');" ><i>🔎︎</i></button>Bismut</h4>
<div id ="zoom_me_hard">
<div class ="r-stack" >
<span class="fragment" data-zoom-trigger='{"selector": "#zoom_me_hard", "scale": 1}'></span>
<!-- <object class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismuth-model2.svg" width="100%"></object> -->
<object class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismuth-Model00.svg" width="70%"></object>
<object id='Bi_result_clustersize' class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismuth-Model00-moving.svg" width="70%"></object>
<!-- <object class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismuth-Model01.svg" width="70%"></object> -->
<object class ="fragment " type="image/svg+xml" data="pictures/Results/Bismuth-Model01-dataPoints.svg" width="70%"></object>
</div>
<div class ="r-stack" >
<object class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismut-kugel-ellipse-kugel0.svg" width="70%"></object>
<object class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismut-kugel-ellipse-kugel1.svg" width="70%"></object>
<object id='Bi_kugel_distortion' class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismut-kugel-ellipse-kugel2.svg" width="70%"></object>
<object id='Bi_kugel_distortion2' class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismut-kugel-ellipse-kugel3.svg" width="70%"></object>
<object class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismut-kugel-ellipse-kugel4.svg" width="70%"></object>
<object id='Bi_kugel_distortion3' class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismut-kugel-ellipse-kugel5.svg" width="70%"></object>
<object id='Bi_kugel_distortion4' class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismut-kugel-ellipse-kugel6.svg" width="70%"></object>
<object id='Bi_kugel_distortion5' class ="fragment current-visible" type="image/svg+xml" data="pictures/Results/Bismut-kugel-ellipse-kugel7.svg" width="70%"></object>
<object class ="fragment" type="image/svg+xml" data="pictures/Results/Bismut-kugel-ellipse-kugel8.svg" width="70%"></object>
</div>
</div>
</div>
</div>
</section>
</section>
<!-- <section data-name="Setup">
<h2>Ultra Hoch Vakuum Anlage</h2>
</section>
<section data-name="Techniken">
<h2></h2>
<div class = 'container'>
<div class = 'col'>
<h2>STM</h2>
</div>
<div class = 'col'>
<h2>UPS</h2>
</div>
</div>
</section>
<section data-name="Resultate">
<h2>Titel</h2>
</section> -->
<section data-visibility="uncounted">
<section data-visibility="uncounted">
<h2>Zusammenfassung</h2>
<div class="col-container" >
<div class="col-one fragment" style="margin-left:10px">
<img src="pictures/ZusammenFassung/Modele-Ueberblick.svg" width="80%"/></img>
<img src="pictures/ZusammenFassung/Pb-Bi-Vergleich.svg" width="100%"/></img>
<div class="left-bottom-under-image"><font size="3"> V. Senz et al., Physical Review Letters. 102, 3–6 (2009)</font></div>
</div>
<div class="col-one" style="margin-left:0px">
<h3 class = "fragment ">Resultate</h3>
<ul class = "fragment " style="font-size:35px;padding:0">
<li>Elektrostatischer Zugang scheint die Systeme gut zu beschreiben</li>
<li>Relativ einfache Methode die Größen Verteilung mit beinhaltet</li>
<li>C<sub>60</sub> "konstante" Größe <br>→ Energie-Shift durch Nachbar-Abschirmung</li>
<li>Bismut variable Größe <br>→ Energie-Shift durch Wechselwirkung mit Ni<sub>3</sub>Al(111)</li>
</ul>
<h3 class = "fragment ">Probleme</h3>
<ul class = "fragment " style="font-size:35px;padding:0">
<li>Interesante Größen-Bereich nicht erreichbar mit der Aufdampf-Methode</li>
<li>Einfluss von Al-Oxide Schicht-Dicke könnte eine Rolle spielen<br>→ Systematische Untersuchungen fehlen</li>
</ul>
<h3 class = "fragment ">Ausblick</h3>
<ul class = "fragment " style="font-size:35px;padding:0">
<li>Massen selektierten Clustern<br>→ Zugang zur kleineren Clustern <br>→ Schmalere größen Verteilung</li>
</ul>
</div>
</div>
</section>
<section id ="old_Zusammenfassung" data-visibility="uncounted">
<h2>Cluster: Potenzial<sup>3</sup></h2>
<img class="fragment" src="pictures/ZusammenFassung/Cluster-Sind-Cool2.svg" width="100%"/></img>
<div class="col-container" ">
<div class="col-one" style="margin-left:0px">
<h3 class = "fragment ">Vorteile:</h3>
<ul class = "fragment " style="font-size:35px">
<li>Drastisch andere Eigenschaften als gleicher Bulk-Material</li>
<li>Mögliche Einstellung der Eigenschaft durch die Größen-Änderung</li>
<li>Vielfalt an Cluster und Cluster-Kombination auf verschieden Materialien</li>
</ul>
</div>
<div class="col-one">
<h3 class = "fragment ">Probleme:</h3>
<ul class = "fragment " style="font-size:35px;padding:0">
<li>Zugang erschwärt durch die Größe</li>
<li>Grössen Kontrolle ist schwierig (Aggregation)</li>
<li>Technologische Prozesse fehlen (Skalierungs-Problem)</li>
</ul>
</div>
</div>
<!-- <div class="col-container" ">
<div class="col-one" style="margin-left:0px">
<img class="fragment" src="pictures/ZusammenFassung/Cluster-Sind-Cool.svg" width="85%"/></img>
</div>
<div class="col-one">
<h3 class = "fragment ">Vorteile:</h3>
<ul class = "fragment " style="font-size:30px">
<li>Drastisch andere Eigenschaften als gleicher Bulk material</li>
<li>Mögliche Einstellung der Eigneschaft durch die Grössen änderung</li>
</ul>
<h3 class = "fragment ">Probleme:</h3>
<ul class = "fragment " style="font-size:30px;padding:0">
<li>Zugang erschwärt durch die Größe</li>
<li>Grössen Kontrolle ist schwirig (Aggregation)</li>
<li>Technologische Prozesse fehlen (Skalierungs-Problem)</li>
</ul>
</div>
</div> -->
</section>
</section>
<!-- <section>
<div style="margin: 500px 0 0 0; font-size:100px;">
Danke
<div>
</section> -->
</section>
</div>
</div>
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